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【向0.2mol/L,200ml的AlCl3溶液中加入300ml的NaOH溶液,产生0.78g沉淀,求NaOH溶液的物质的量的浓度?】
题目内容:
向0.2mol/L,200ml的AlCl3溶液中加入300ml的NaOH溶液,产生0.78g沉淀,求NaOH溶液的物质的量的浓度?优质解答
(1)当NaOH溶液不足时:
AlCl3 + 3NaON === Al(OH)3↓ +3NaOH
3 mol 78 g
n1 0.78g
n1 = 0.03mol
C(NaOH) = 0.03mol÷0.3L
=0.1mol/L
(2) 当NaOH溶液过量时:
AlCl3 + 3NaON === Al(OH)3↓ +3NaOH
1mol 3mol 78g
0.04mol n2 m
n2 = 0.12mol
m = 3.12g
NaON + Al(OH)3 === NaAlO2 + 2H2O
1mol 78g
n3 3.12 -0.78 g
n3 = 0.03mol
C(NaOH) = (0.12 mol+ 0.03mol)÷0.3L
= 0.5mol/L
答:略
优质解答
AlCl3 + 3NaON === Al(OH)3↓ +3NaOH
3 mol 78 g
n1 0.78g
n1 = 0.03mol
C(NaOH) = 0.03mol÷0.3L
=0.1mol/L
(2) 当NaOH溶液过量时:
AlCl3 + 3NaON === Al(OH)3↓ +3NaOH
1mol 3mol 78g
0.04mol n2 m
n2 = 0.12mol
m = 3.12g
NaON + Al(OH)3 === NaAlO2 + 2H2O
1mol 78g
n3 3.12 -0.78 g
n3 = 0.03mol
C(NaOH) = (0.12 mol+ 0.03mol)÷0.3L
= 0.5mol/L
答:略
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